Homogeneous and heterogeneous

Pure theoretically calculating we could distinguish 18 kinds of mixtures of two components, if we apply:
  1. having three different phases,
  2. the mixture is composed of two components, and
  3. every mixture can be homogeneous as well as heterogeneous.

(s)
(l)
(g)
(s)
(s) + (s) (s) + (l) (s) + (g)
(l)
(l) + (s) (l) + (l) (l) + (g)
(g)
(g) + (s) (g) + (l) (g) + (g)

The scheme shows nine theoretical mixtures that all can be (also theoretically) homo and heterogeneous. Note that the reality is different.
  1. (l) + (s)     and     (s) + (l) are equal.
  2. (g) + (g) is always homogeneous; there is no heterogeneous form of it.
  3. (g) + (s) only exist as heterogeneous mixtures.


A couple of examples: